Structural resolution. Condiitions for
systematic absences
In
another chapter
reference has been made to the fact that in order to solve the internal
structure of a crystal it is necessary to know its approximate chemical
composition, the dimensions of the unit cell, the diffraction
intensities, and the symmetry of the crystal. Well, it seems reasonable
to assume that the internal symmetry of a crystal (the space group)
could hardly be inferred from observing its external habit. In fact,
the
crystal symmetry can only be deduced from the diffraction
pattern
itself, since certain crystal symmetry operations leave some
type
of trace in the diffraction pattern, systematically canceling certain
intensities that follow the rules that are shown below (some of these
rules were explained in another
section):
But let's go back...